Reduction of water-molecule-induced current-voltage hysteresis in graphene field effect transistor with semi-dry transfer using flexible supporter
Jung, Sungchul
;
Yoon, Hoon Hahn
;
Jin, Hanbyul
;
Mo, Kyuhyung
;
Choi, Gahyun
;
Lee, Junghyun
;
Park, Hyesung
;
Park, Kibog
초록
The polymethyl methacrylate-assisted wet transfer method of chemical vapor deposition (CVD) graphene has been widely used, thanks to its good coverage and simplicity. However, in the wet-transfer method, water molecules are inevitably trapped between the graphene and the substrate because the graphene is transferred to the substrate while floating in water. The trapped water molecules can cause the unwanted doping of graphene and hysteretic behavior in the current-voltage (I-V) curve. We here propose a new semidry transfer method using the Kapton tape as an additional flexible supporting layer. The N 2 blowing and heating processes are added to vaporize the water molecules adsorbed on graphene layer right before the transfer step. By comparing the I-V characteristics of wet- and semidry-transferred graphene field effect transistor (GFET), the field effect mobility is found to be larger for the semidry-transferred GFET in comparison with the wet-transferred one, possibly due to the more uniform Coulomb potential landscape. Most importantly, the hysteretic behavior is found to be reduced in accordance with the decrease of the trapped water molecules. The averaged electron mobilities obtained from the GFET measurements are 1118 c m 2 / V s and 415 c m 2 / V s for semidry- and wet-transferred graphene, respectively. Our semidry transfer method can provide a simple and reliable way to transfer the CVD graphene onto an arbitrary substrate with the minimized number of trapped water molecules, which is readily applicable for large-scale substrates with potential of commercialization.
Highly Enantioselective Graphene-Based Chemical Sensors Prepared by Chiral Noncovalent Functionalization
Shang, Xiaobo
;
Park, Cheol Hee
;
Jung, Gwan Yeong
;
Kwak, Sang Kyu
;
Oh, Joon Hak
초록
As a basic characteristic of the natural environment and living matter, chirality has been used in various scientific and technological fields. Chiral discrimination is of particular interest owing to its importance in catalysis, organic synthesis, biomedicine, and pharmaceutics. However, it is still very challenging to effectively and selectively sense and separate different enantiomers. Here, enantio-differentiating chemosensor systems have been developed through spontaneous chiral functionalization of the surface of graphene field-effect transistors (GFETs). GFET sensors functionalized using noncovalent interactions between graphene and a newly synthesized chiral-functionalized pyrene material, Boc-L-Phe-Pyrene, exhibit highly enantioselective detection of natural acryclic monoterpenoid enantiomers, that is, (R)-(+)- and (S)-(-)-beta-citronellol. On the basis of a computational study, the origin of enantio-differentiation is assigned to the discriminable charge transfer from (R)-(+)- or (S)-(-)-beta-citronellol into graphene with a significant difference in binding strength depending on surface morphology. The chemosensor system developed herein has great potential to be applied in miniaturized and rapid enantioselective sensing with high sensitivity and selectivity.
Integrated arrays of air-dielectric graphene transistors as transparent active-matrix pressure sensors for wide pressure ranges
Shin, Sung-Ho
;
Ji, Sangyoon
;
Choi, Seiho
;
Pyo, Kyoung-Hee
;
An, Byeong Wan
;
Park, Jihun
;
Kim, Joohee
;
Kim, Ju-Young
;
Lee, Ki-Suk
;
Kwon, Soon-Yong
;
Heo, Jaeyeong
;
Park, Byong-Guk
;
Park, Jang-Ung
초록
Integrated electronic circuitries with pressure sensors have been extensively researched as a key component for emerging electronics applications such as electronic skins and healthmonitoring devices. Although existing pressure sensors display high sensitivities, they can only be used for specific purposes due to the narrow range of detectable pressure (under tens of kPa) and the difficulty of forming highly integrated arrays. However, it is essential to develop tactile pressure sensors with a wide pressure range in order to use them for diverse application areas including medical diagnosis, robotics or automotive electronics. Here we report an unconventional approach for fabricating fully integrated active-matrix arrays of pressure-sensitive graphene transistors with air-dielectric layers simply formed by folding two opposing panels. Furthermore, this realizes a wide tactile pressure sensing range from 250 Pa to similar to 3MPa. Additionally, fabrication of pressure sensor arrays and transparent pressure sensors are demonstrated, suggesting their substantial promise as next-generation electronics.
Dirac Voltage Shift of Graphene Transistors According to the Composition of Copolymer Dielectrics Deposited Via Initiated Chemical Vapor Deposition
Pak, Kwanyong
;
Oh, Joong Gun
;
Kim, Choong Sun
;
Cho, Byung-Jin
;
Im, Sung Gap
Integrated Arrays of Air-Dielectric Graphene Transistors as Transparent, Active-Matrix Pressure Sensors for Wide Pressure Ranges
Ji, Sangyoon
;
Kim Joohee
;
Jang Jiuk
;
Park, Jang-Ung
Integrated Active-Matrix Pressure Sensors Using Air-Dielectric Graphene Transistors with Wide Pressure Ranges
Shin, Sungho
;
Ji, Sangyoon
;
An, Byeong Wan
;
Park, Jang-Ung
초록
학술대회명
The 4th International Conference on Electronic Materials and Nanotechnology for Green Environment (ENGE 2016)